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Properties of New Zirconia-based Composites for Glass Kilns

作者:LIANG Xinxing1YE Hang2GAO Yuying3ZHAN Lei2,4MA Chengliang3LIU Xiaogang1FAN Chongfang1XU Enxia3DING Qiang2LI Yongsheng4

作者单位:1.Zhengzhou Fangming High Temperature Ceramic New Material Co., Ltd.2.RHI Magnesita (China) Co., Ltd.3.School of Material Science and Engineering, Henan Key Laboratory of High Temperature Functional Materials, Zhengzhou University4.School of Materials Science and Technology, East China University of Science and Technology

刊名:China's Refractories

ISSN:1004-4493

出版年:2024-12-15

卷:33

期:4

起页:29-33

止页:

分类号:TQ171.623;TQ175.7

语种:英文

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内容简介

To provide a material with excellent comprehensive properties for the glass kiln melting pools, zirconia powder and alumina powder were fully mixed according to the ratio of m(Zr O2) : m(Al2O3)=4 : 1 and fused in an arc furnace. The obtained fused zirconia-corundum eutectic material was processed into different particle sizes, batched according to a certain particle size distribution and mixed evenly. After pressure molding and firing at 1 750 °C, new zirconia-based composites were prepared.The phase composition and microstructure of the composites were analyzed. The molten glass corrosion resistance of the composites was compared with that of zirconia corundum bricks 33# and 41#. The results show that the new zirconia-based composites have a dense structure, high chemical purity without low melting point components, and good thermal shock resistance. Compared with zirconia corundum bricks 33# and 41#, after being corroded by high temperature molten glass, the new composites have no corrosion cavities, needle-like pores, defects or liquid phase infiltration, and no reaction with molten glass, showing good corrosion resistance to molten glass.

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