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Effect of Silicon Addition on Microwave Synthesis of Al4SiC4

作者:WANG Li,LIU Shijie,WEI Haoyu,MA Juanjuan,DONG Binbin,GENG Shangrui,YAN Miaoxin,QIN Feng,GUO Yusen

作者单位:Luoyang Institute of Science and Technology

刊名:China's Refractories

ISSN:1004-4493

出版年:2024-12-15

卷:33

期:4

起页:9-13

止页:

分类号:TQ175.7

语种:英文

关键词:

内容简介

Al4SiC4 was prepared using Al powder, silicon carbide powder, and graphite as raw materials, and silicon as the additive by microwave sintering. Effects of silicon additions(0, 5%, 10% and 15%, by mass) on the phase composition, microstructure,apparent porosity and bulk density of the Al4SiC4 sample prepared with different aluminum additions(20%, 25%, by mass)were researched. Then the developed Al4SiC4 samples were applied to MgO-C bricks to investigate the effect on the oxidation resistance and mechanical properties of the MgO-C bricks. The results show that Al4SiC4 can be synthesized at lower temperatures using the microwave sintering method. The sample with 20% aluminum addition has a lower Al4SiC4 content than the one with 25% aluminum. When the silicon addition is 10% and the aluminum addition is 25%, the sample appears needlelike system, the porosity is only 28.69%, and the sample is dense. The developed Al4SiC4 was added into MgO-C bricks as the antioxidant, which greatly increased the oxidation resistance and the mechanical properties of the MgO-C bricks.

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