第2期
Steam Oxidation Resistance Comparison of Several Silicon Carbide Refractories at Elevated Temperatures
作者:WANG Jiaping*, WU Jiguang, HUANG Zhigang, LYU Chunjiang, WANG Wenwu
作者机构:Sinosteel Luoyang Institute of Refractories Research Co., Ltd., Luoyang 471039, China
分类号:
卷号:
期号 : 2023 年, 第2期
页码:18 - 23
内容简介

The oxidation tests of different SiC refractories including Si3N4-SiC bricks, Si3N4-Si2N2O-SiC bricks from China (SNO-1), Si3N4-Si2N2O-SiC bricks from overseas (SNO-2), SiAlON-SiC bricks, oxides bonded SiC bricks, self-bonded SiC bricks as well as SiC castables were carried out in the steam atmosphere (1 000 , 32 kg · m-3 · h -1) for different durations (100, 200, 300, 400 and 500 h). The mass, the volume, the bulk density and the apparent porosity before and after the oxidation were tested. The XRD and SEM analyses were conducted. The results indicate that: (1) under the steam atmosphere condition (1 000 , 32 kg · m-3 · h-1), as the oxidation time increases from 0 to 500 h, the volume and the mass of the silicon carbide refractories increase, while the bulk density decreases; in terms of the apparent porosity, oxides bonded SiC bricks and SiC castables present an increasing trend, Si3N4-SiC bricks, SiAlON-SiC bricks and self-bonded SiC bricks present an increasing trend first and then a decreasing trend, and Si3N4-Si2N2O-SiC bricks present a decreasing trend or a trend of decreasing first and then increasing; (2) as for Si3N4-Si2N2O-SiC bricks, SNO-1 and SNO-2 have basically the same chemical and phase composition, SNO-2 has the lower mass change rate than SNO-1 during oxidation from 200-500 h, which indicates that SNO-2 has the better steam oxidation resistance than SNO-1.

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