To meet the needs of environmental protection and promote the application of chromium-free refractories for RH refining furnaces, research on application of new non-burned periclase-magnesia alumina spinel bricks was carried out. Through laboratory research and field application, it is concluded that the non-burned periclase-magnesia alumina spinel brick can replace magnesia-chrome material, and its service life is equivalent to that of the magnesia-chrome material with reduced cost.