第4期
Suggestions for Sintering Technologies of High Cr2O3
作者:QIAN Yuejin, YU Xingguo, JIANG Mingxue, LI Liusheng
作者机构:The Department of Material Science and Engineering, Luoyang Institute of Science
分类号:
卷号:21
期号 : 2012 年, 第4期
页码:22 - 26
内容简介

Cr2O3 can be sintered well at 1 500 in carbon-embedded condition or H2 atmosphere. But the high chrome bearing refractories can not reach densification when sintered at 1 700 for 10 h in weak reducing atmosphere formed by the combustion of fuel, and its apparent porosity is about 18. The high chrome bearing refractories are mainly used in coal gasifiers. The temperature in the furnace is about 1 500 and the products are H2 and CO, which are just the sintering conditions of the dense chrome refractories with apparent porosity less than 10%. The high chrome bearing refractories used in coal gasifiers may be sintered again and then shrink, destroying the gasifier lining. The thermodynamic calculation shows that it is safe about the high chrome bearing refractories used in gasifiers. It is also explained that the high chrome bearing refractories cant be sintered densely in weak reducing atmosphere formed by the combustion of fuel. The new sintering technologies can be used to improve the bulk density of the high chrome bearing refractories.

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