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Effect of CaO/SiO2 Slag Mass Ratio on Dissolution Rate of Alumina-based Refractory Ceramics

作者:ZENG Fanbo,HUANG Ao,WANG Xinlian,LI Shenghao,ZHANG Shuzhe,QU Pengcheng,GU Huazhi

作者单位:The State Key Laboratory of Refractories and Metallurgy,Wuhan University of Science and Technology

刊名:China’s Refractories

ISSN:1004-4493

出版年:2023-03-15

卷:32

期:1

起页:30-34

止页:

分类号:TQ175.7

语种:英文

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内容简介

The dissolution of alumina-based refractory ceramics in CaO-Al2O3-SiO2 slag melts was performed based on the in-situ observation system of an ultra-high-temperature laser confocal microscope,and the effect of the CaO/SiO2 slag mass ratio(C/S ratio) on the dissolution rate of alumina-based refractory ceramics was investigated.The results indicate that the dissolution rate increases with an increase of the C/S ratio and is mainly controlled by diffusion.During the early stage of dissolution,for all C/S ratios,the dissolution process conforms to the classical invariant interface approximation model.During the later stage of dissolution,when the C/S ratio is ≥6,the dissolution process is significantly different from the model above because of the formation of a thick interfacial layer,which can be explained by dissolution kinetics.

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